Hybrid Metal Oxide/Biochar Materials for Wastewater Treatment Technology: A Review

This paper discusses the properties of metal oxide/biochar systems for use in wastewater treatment. Titanium, zinc, and iron compounds are most often combined with biochar; therefore, combinations of their oxides with biochar are the focus of this review. The first part of this paper presents the most important information about biochar, including its advantages, disadvantages, and possible modification, emphasizing the incorporation of inorganic oxides into its structure. In the next four sections, systems of biochar combined with TiO₂, ZnO, Fe₃O₄, and other metal oxides are discussed in detail. In the next to last section probable degradation mechanisms are discussed. Literature studies revealed that the dispersion of a metal oxide in a carbonaceous matrix causes the creation or enhancement of surface properties and catalytic or, in some cases, magnetic activity. Addition of metallic species into biochars increases their weight, facilitating their separation by enabling the sedimentation process and thus facilitating the recovery of the materials from the water medium after the purification process. Therefore, materials based on the combination of inorganic oxide and biochar reveal a wide range of possibilities for environmental applications in aquatic media purification.