Caught while Dissolving: Revealing the Interfacial Solvation of the Mg²⁺ Ions on the MgO Surface

Interfaces between water and materials are ubiquitous and are crucial in materials sciences and in biology, where investigating the interaction of water with the surface under ambient conditions is key to shedding light on the main processes occurring at the interface. Magnesium oxide is a popular model system to study the metal oxide-water interface, where, for sufficient water loadings, theoretical models have suggested that reconstructed surfaces involving hydrated Mg²⁺ metal ions may be energetically favored. In this work, by combining experimental and theoretical surface-selective ambient pressure X-ray absorption spectroscopy with multivariate curve resolution and molecular dynamics, we evidence in real time the occurrence of Mg²⁺ solvation at the interphase between MgO and solvating media such as water and methanol (MeOH). Further, we show that the Mg²⁺ surface ions undergo a reversible solvation process, we prove the dissolution/redeposition of the Mg²⁺ ions belonging to the MgO surface, and we demonstrate the formation of octahedral [Mg(H₂O)₆]²⁺ and [Mg(MeOH)₆]²⁺ intermediate solvated species. The unique surface, electronic, and structural sensitivity of the developed technique may be beneficial to access often elusive properties of low-Z metal ion intermediates involved in interfacial processes of chemical and biological interest.