Mechanism and performance of ionic diodes fabricated from 2D trapezoidal-shaped nanochannels

Bioinspired asymmetric two-dimensional (2D) nanochannels with ionic diode behavior are highly desirable, as they can be constructed and modified easily. However, the knowledge about the rectification mechanism of the nanochannels is still very limited. In this paper, the ionic current rectification (ICR) of the 2D trapezoidal-shaped nanochannels was studied both numerically and experimentally. A multi-physics model, considering the electric field, the ion concentration field, and the flow field, was built for simulating the ion transportation inside the nanochannels. With a limited channel height, the 2D nanochannels are counter-ion selective; therefore, under an external electric field, the accumulation of co-ions takes place at one end of the nanochannels. By introducing shape asymmetry to the nanochannels, the ICR was achieved due to the asymmetric ion concentration polarization at two ends of the nanochannels under opposite electric fields. The structure of the nanochannels, the surface charge density of the nanochannel walls, and the ionic strength of the working fluids affect the ICR of the ionic diodes by changing the ion concentration polarization at two ends of the nanochannels. In the experiment, the current-voltage curves of the nanochannel arrays fabricated by assembling graphene oxide nanosheets were measured, which are in accordance with the numerical results. This paper provides a comprehensive understanding of the mechanism of the 2D trapezoidal-shaped ionic diodes, which may act as a guideline for the design and optimization of ionic diodes.