Giant Thermoelectric Power Factor Anisotropy in PtSb_1.4Sn_0.6

We report on the giant anisotropy found in the thermoelectric power factor (S²σ) of marcasite structure-type PtSb_1.4Sn_0.6 single crystal. PtSb_1.4Sn_0.6, synthesized using an ambient pressure flux growth method upon mixing Sb and Sn on the same atomic site, is a new phase different from both PtSb₂ and PtSn₂, which crystallize in the cubic Pa3̅ pyrite and Fm3̅m fluorite unit cell symmetry, respectively. The large difference in S²σ for heat flow applied along different principal directions of the orthorhombic unit cell stems mostly from anisotropic Seebeck coefficients.