The dewatering performance and cracking-flocculation-skeleton mechanism of bioleaching-coal fly ash combined process...

High water content in sludge will affect the transportation and subsequent disposal of sludge. Bioleaching is a biological sludge conditioning technology, which can effectively improve the dewatering performance of sludge and reduce the content of heavy metals in sludge. Coal fly ash, as a skeleton builder, can also improve the dewatering performance of sludge. In this study, bioleaching combined with coal fly ash (BL-CFA) process was employed to improve sludge dewatering performance. Based on the results of response surface methodology (RSM), the capillary suction time (CST) and water content (WC) of sludge decreased by 52.27% and 38.92%, respectively. The dewatering effect of BL-CFA is superior compared with single process. For extracellular polymeric substances (EPS), the content of protein and polysaccharide in tightly and loosely EPS (TB-EPS and LB-EPS) of sludge decreased after BL-CFA process, while that in soluble EPS (S-EPS) increased. Three-dimensional fluorescence indicated that the weakened fluorescent areas of proteinoid and soluble microbial by-product-like (SMP) organic in LB-EPS and TB-EPS, which is beneficial to the improvement of sludge dewatering performance. Fourier transform infrared (FTIR) spectroscopy showed that the polysaccharides and proteins in the sludge were cleaved and released into the supernatant after BL-CFA process. The variation of particle size revealed that flocculation occurred after adding CFA into acidified sludge, and a supporting structure was formed in the sludge with the assist of CFA through the analysis of the scanning electron microscopy (SEM). Based on the above results, a triple dehydration mechanism was proposed for BL-CFA process, namely, cracking-flocculation-skeleton construction, which endows the combined process with superior sludge dewatering effect and application potential.