Influence of different kinds of incinerators on PCDD/Fs: a case study of emission and formation pathway

Few studies focused on the emission of polychlorinated-ρ-dibenzodioxins and dibenzofurans (PCDD/F) from different kinds of waste incinerators. This study was conducted in a full-scale MSW incineration plant to investigate the influence of different incinerator types on PCDD/F. Experimental results indicated that the 2,3,7,8-PCDD/F concentration in the inlet gas of the air pollution control system (APCS) in the studied fluidized bed was higher (2.03 ng I-TEQ/Nm³) than that of the grate (0.77 ng I-TEQ/Nm³). But gas in the outlet of APCS from both incinerators had an approximate concentration, lower than the Chinese emission limit of 0.1 ng I-TEQ/Nm³. Similar distribution patterns were observed for 2,3,7,8-PCDD/Fs, as well as 136 PCDD/F congeners. Specifically, OCDD and 1,2,3,4,6,7,8-HpCDD were major isomer constituents for 2,3,7,8-PCDD/F isomers. In terms of formation pathways, a similar formation mechanism was observed based on fingerprint characteristics of 136 PCDD/F congeners. De novo synthesis was the dominating formation pathway for both incinerators. Meanwhile, DD/DF chlorination was another contributor to PCDD/F formation, which in the fluidized bed was higher. In addition, little correlation (0.009 < R² < 0.533) between conventional pollutants (HCl, CO, PM) and PCDD/Fs was found, suggesting little high-temperature synthesis observed and verifying the dominance of de novo synthesis.