Magnetic Stuffed Bun-Structured Metal-Organic Framework Monoliths with Noncompromised Accessible Pores and Highly...

Development of industrially favorable metal-organic framework (MOF) monoliths is of paramount importance for their real-world applications. However, MOF monoliths prepared with the existing MOF shaping methods usually have seriously compromised accessible pores and suffer from inefficient and energy-intensive recycling, thereby greatly limiting their practical applications. We herein present a magnetic stuffed bun-structured MOF (mSBM) bead consisting of highly porous poly(vinyl alcohol) wraps stuffed with a binder-free powder mixture of UiO-66 and Fe₃O₄ nanoparticles. Such a unique structure and composition of the mSBM not only make its MOF component have a well-reserved crystal structure, surface area, and porosity and the corresponding accessible pores but also impart it with excellent localized magnetic induction heating (LMIH) capability that enables the sufficient heating and highly efficient recycling of the mSBM. These merits of mSBMs are further exemplified by assessing their atmospheric water adsorption and LMIH-driven water desorption performance. The mSBMs exhibit well-reserved atmospheric water adsorption capacities, up to 100% LMIH-driven water desorption, excellent reusability, and durability toward the practical applications. Our current work, therefore, demonstrates a new MOF shaping strategy to produce MOF monoliths with well-defined shapes, noncompromised accessible pores, and highly efficient recycling capabilities, paving a bright avenue to accelerate the practical applications of MOF monoliths.