Gas-phase and PM_2.5-bound phthalates in nail salons: characteristics, exposure via inhalation, and influencing...

This study aimed to investigate the characteristics of, exposure to, and factors influencing gas-phase and PM_2.5-bound phthalates (PAEs) in nail salons. Data on both indoor and outdoor gas-phase and PM_2.5-bound PAEs, carbon dioxide (CO₂), temperature, and relative humidity were collected in nail salons. We also used questionnaires to survey building characteristics and occupants' behaviors. The average total gas-phase and PM_2.5-bound PAE concentrations indoors were higher than those outdoors by 6 and 3 times, respectively. Diethyl phthalate, diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), and di-(2-ethylhexyl) phthalate (DEHP) were the predominant compounds among both the gas-phase and PM_2.5-bound PAEs in indoor air. The volume of the salon's space or the difference of indoor and outdoor CO₂ concentrations (dCO₂) was significantly associated with indoor PAE concentrations. The ratios of PM_2.5-bound to gas-phase PAEs, especially high-molecular-weight PAEs, were positively associated with the dCO₂ concentrations. Higher ratios of indoor to outdoor PM_2.5-bound DiBP, DnBP, and DEHP concentrations were discovered when more clients visited each day. Building characteristics, ventilation conditions, and occupants' activities have influences on the gas-phase and particle-phase PAEs. The study identifies the characteristics of gas-phase and PM_2.5-bound PAEs in nail salons and their influencing factors.