Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.4K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.4K
Alkyl Halides02:45

Alkyl Halides

17.2K
Structural Properties
Alkyl halides are halogen-substituted alkanes wherein one or more hydrogen atoms of an alkane is replaced by a halogen atom such as fluorine, chlorine, bromine, or iodine. The carbon atom in an alkyl halide is bonded to the halogen atom, which is sp3-hybridized and exhibits a tetrahedral shape.
Unlike alkyl halides, compounds in which a halogen atom is bonded to an sp2 -hybridized carbon atom of a carbon-carbon double bond (C=C) are called vinyl halides. Whereas aryl...
17.2K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.9K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.9K
Trends in Lattice Energy: Ion Size and Charge02:54

Trends in Lattice Energy: Ion Size and Charge

24.2K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
24.2K
Electrolytes: van't Hoff Factor03:08

Electrolytes: van't Hoff Factor

33.5K
Colligative Properties of Electrolytes
The colligative properties of a solution depend only on the number, not on the identity, of solute species dissolved. The concentration terms in the equations for various colligative properties (freezing point depression, boiling point elevation, osmotic pressure) pertain to all solute species present in the solution. Nonelectrolytes dissolve physically without dissociation or any other accompanying process. Each molecule that dissolves yields one...
33.5K
Ionic Crystal Structures02:42

Ionic Crystal Structures

14.6K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.6K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A nickel/cobalt-free Mn-based layered oxide cathode based on an orbital hybridization modulation strategy for high energy density sodium-ion batteries.

Chemical science·2026
Same author

Constructing Face-Shared Configuration at the Hetero-Interface in Li-Rich Layered Oxide Cathodes.

Angewandte Chemie (International ed. in English)·2026
Same author

Dual-functional structural modulation for stabilizing sodium layered oxide cathodes.

Chemical communications (Cambridge, England)·2026
Same author

High-voltage and stable co-free LiNiO<sub>2</sub> positive electrode for sulfide-based all-solid-state batteries.

Nature communications·2026
Same author

Ferroelectric-Field-Steered SEI Engineering for Long-Life Lithium-Metal Batteries.

Angewandte Chemie (International ed. in English)·2025
Same author

Spatially Selective Substitution for Structural Stabilization of Sodium Layered Oxide Cathodes.

Angewandte Chemie (International ed. in English)·2025
Same journal

An integrated annotation strategy for the phytochemical characterization of Xie-Bai-San decoction based on UPLC-Q Exactive Orbitrap HRMS, multi-database screening, and feature-based molecular networking.

Frontiers in chemistry·2026
Same journal

Core-shell structured nanomaterials in dual-modal magnetic resonance imaging guided antitumor effect via combined treatment.

Frontiers in chemistry·2026
Same journal

Photo-responsive nanozymes: from photocatalytic mechanisms to precision therapy.

Frontiers in chemistry·2026
Same journal

From theoretical energy to practical utilization: interfacial stability, transport kinetics, and cell-level design in high-energy lithium-metal batteries.

Frontiers in chemistry·2026
Same journal

Zinc-vacancy defects in ZnO nanorods induced visible-light activity of photoelectrochemical glucose sensing: experimental and DFT+U analysis.

Frontiers in chemistry·2026
Same journal

Integrating multi-isotope calibration and infrared-assisted digestion for robust and sustainable multielemental determination in agroalimentary matrices by ICP-MS.

Frontiers in chemistry·2026
See all related articles

Related Experiment Video

Updated: Aug 31, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

21.8K

Temperature-dependent compatibility study on halide solid-state electrolytes in solid-state batteries.

Gaoshuai Jia1, Zhi Deng1, Dixing Ni1

  • 1Department of Physics and Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen, China.

Frontiers in Chemistry
|August 22, 2022
PubMed
Summary
This summary is machine-generated.

All-solid-state lithium batteries (ASSLBs) require compatible interfaces. Rock-salt Li3InCl6 shows better thermal stability and interfacial compatibility than anti-perovskite Li2OHCl in ASSLBs.

Keywords:
anti-perovskitehalideinterfacial compatibilityrock-saltsolid-state batterysolid-state electrolytethermal stability

More Related Videos

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
11:04

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

13.1K
Ultrasound Velocity Measurement in a Liquid Metal Electrode
08:41

Ultrasound Velocity Measurement in a Liquid Metal Electrode

Published on: August 5, 2015

11.8K

Related Experiment Videos

Last Updated: Aug 31, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
05:33

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

21.8K
Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
11:04

Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature

Published on: December 20, 2016

13.1K
Ultrasound Velocity Measurement in a Liquid Metal Electrode
08:41

Ultrasound Velocity Measurement in a Liquid Metal Electrode

Published on: August 5, 2015

11.8K

Area of Science:

  • Materials Science
  • Electrochemistry
  • Solid-State Batteries

Background:

  • All-solid-state lithium batteries (ASSLBs) offer enhanced safety and energy density over conventional batteries.
  • Interfacial compatibility between solid-state electrolytes (SSEs) and electrodes remains a critical challenge.
  • Halide SSEs are promising due to their relatively good interfacial properties.

Purpose of the Study:

  • To investigate the temperature-dependent interfacial compatibility of halide SSEs in ASSLBs.
  • To evaluate the thermal stability and chemical reactivity of specific halide SSEs with common battery electrode materials.
  • To provide insights for selecting compatible materials for advanced ASSLBs.

Main Methods:

  • Simultaneous thermogravimetry and differential scanning calorimetry (TG-DSC) for thermal analysis.
  • X-ray diffraction (XRD) to study structural changes and phase compatibility.
  • Testing of halide SSEs (Li3InCl6, Li2OHCl) with oxide and other electrode materials.

Main Results:

  • Both Li3InCl6 and Li2OHCl exhibit good thermal stability with LiCoO2, LiMn2O4, and Li4Ti5O12 up to 320°C.
  • Anti-perovskite Li2OHCl shows increased chemical reactivity with materials like LiFePO4 and Si-C upon melting at 320°C.
  • Rock-salt Li3InCl6 demonstrates superior stability and interfacial compatibility across tested conditions.

Conclusions:

  • Rock-salt-type Li3InCl6 is a more suitable halide SSE for ASSLBs due to its higher chemical stability and compatibility.
  • Anti-perovskite Li2OHCl's reactivity post-melting limits its application with certain electrode materials.
  • Understanding interfacial behavior is crucial for designing robust and efficient ASSLBs.