Enhanced the synergistic degradation effect between active hydroxyl and reactive oxygen species for indoor...

Maintaining high activity during prolonged catalysis is always the pursuit in catalytic degradation of organic pollutants. For indoor formaldehyde (HCHO) degradation, the accumulation of intermediates is the major factor limiting the conversion of HCHO to final product CO₂ (HCHO-to-CO₂ conversion) and long-lasting catalysis. Herein, a three-dimensional radialized nanostructure catalyst self-assembled by MnOOH/MnO₂ nanosheets anchored with Pt single atoms (Pt_SA-MnOOH/MnO₂ with a trace platinum loading amount of 0.09%) is developed by thermally assisted two-step electrochemical method, which achieves enhanced CO₂ production in catalytic HCHO degradation at the room temperature by the collaborative action of active hydroxyl (OH*) and active oxygen species (O₂*). By boosting intermediates' decomposing, the catalyst implements real-time HCHO-to-CO₂ conversion (∼85.7%) and long-term continuous HCHO removal (∼98%) during 100 h in a 15 ppm HCHO atmosphere at 25 °C under a weight hourly space velocity of 30000 mL/g_cat∙h. Density functional theory calculation shows that the formation energy of O₂* from O₂ over Pt_SA-MnOOH/MnO₂ is nearly half lower than that over Pt-MnO₂ catalyst. And decomposing accumulated intermediates gives the credit to OH* species sustainably generated by the combined action of MnOOH and O₂*. The synergistic action between Pt_SA and MnOOH contributes to the continuous production of O₂* and OH* for enhancing CO₂ production in indoor catalytic formaldehyde degradation.