Synthesis and CO₂ Capture of Porous Hydrogel Particles Consisting of Hyperbranched Poly(amidoamine)s

We successfully synthesized new macroporous hydrogel particles consisting of hyperbranched poly(amidoamine)s (HPAMAM) using the Oil-in-Water-in-Oil (O/W/O) suspension polymerization method at both the 50 mL flask scale and the 5 L reactor scale. The pore sizes and particle sizes were easily tuned by controlling the agitation speeds during the polymerization reaction. Since O/W/O suspension polymerization gives porous architecture to the microparticles, synthesized hydrogel particles having abundant amine groups inside polymers exhibited a high CO₂ absorption capacity (104 mg/g) and a fast absorption rate in a packed-column test.