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Sponge-Like Microfiber Electrodes for High-Performance Redox Flow Batteries.

Jing Sun1, Yuhan Wan1, Qinping Jian1

  • 1Department of Mechanical and Aerospace Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, 999077, China.

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|August 25, 2022
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Summary
This summary is machine-generated.

Researchers developed advanced carbon microfiber electrodes for redox flow batteries. These electrodes offer high surface area and permeability, boosting battery efficiency and longevity for energy storage applications.

Keywords:
cross-linking electrospinningfiber diameterporous carbon fibersredox flow batteriesspecific surface area

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Developing high-performance redox flow batteries requires electrodes with large specific surface area and high flow permeability.
  • Current electrode fabrication methods face challenges in balancing these properties.

Purpose of the Study:

  • To fabricate novel sponge-like microfiber carbon electrodes for enhanced redox flow battery performance.
  • To investigate the electrochemical properties and long-term stability of these electrodes.

Main Methods:

  • Electrospinning of cross-linked poly(vinyl alcohol)-lignin-polytetrafluoroethylene precursors.
  • Oxidation and pyrolysis of the electrospun fibers to form carbon microfibers.
  • Characterization of surface area, fiber diameter, and macropore size.
  • Testing in a vanadium redox flow battery system.

Main Results:

  • Achieved a specific surface area of 853.6 m² g⁻¹ with fiber diameters of 5-7 µm and macropores of ≈26.8 µm.
  • Vanadium redox flow battery demonstrated 79.1% energy efficiency at 400 mA cm⁻².
  • Exhibited excellent capacity retention of 99.94% over 2000 cycles.

Conclusions:

  • The developed sponge-like porous carbon microfibers are highly effective for redox flow batteries.
  • This fabrication strategy offers a promising approach for advanced energy storage systems.
  • The electrodes provide a superior balance of surface area and permeability for efficient battery operation.