The Microstructure Evolution Process and Flexural Behaviours of SiC Matrix Ceramic Infiltrated by Aluminium Base...

In this paper, an infiltration approach was proposed to generate a Ti₃Si(Al)C₂ transition layer in SiC matrix composites to effectually strengthen SiC ceramics. The infiltration temperature played a significant role in the evolution of the microstructure, phase composition, and flexural behaviours. Molten aluminium base alloy fully penetrated SiC ceramic after infiltration at different experimental temperatures (800-1000 °C). The phases in the reaction layer on the surface of SiC ceramic samples varied with the infiltration temperature. When infiltrated at 800 °C, only SiC and Al phases can be found in SiC composites, whereas at 900 °C, a reaction layer containing Ti₃Si(Al)C₂ and SiC was produced. The Ti₃Si(Al)C₂ phase grew in situ on SiC. At 1000 °C, the Ti₃Si(Al)C₂ phase was unstable and decomposed into TiC and Ti₅Si₃. The cermet phase Ti₃Si(Al)C₂ was synthesized at a relatively low temperature. Consequently, the flexural modulus and three-point bending strength of samples infiltrated at 900 °C was enhanced by 1.4 and 2.4 times for the original SiC ceramic, respectively.