Durability of Recycled Concrete Aggregates Prepared with Mechanochemical and Thermal Treatment

Recycled concrete aggregates (RCAs) have low quality when compared with natural or conventional aggregates as the paste adhering to it is the key aspect that affects its functionality. Since the adhering cementitious paste weakens the adhesion between the aggregate and the binder, it becomes a decisive factor in the mechanical behavior of the asphalt mixture. It turns out that enhancing the surface of the aggregate or eliminating the paste attached to the NA (natural aggregate) is crucial for improving interfacial bonding. Therefore, the treatment and evaluation of the RCAs by laboratory testing method were studied in this research to assess their reuse in the asphalt pavement surface coarse layer. With the various techniques for removing paste from the RCA, a combination of three enhancement processes were developed for the effective removal of the cement paste, which are mechanical, chemical, and 400 °C conditioning thermal treatment. The RCAs were first charged in a Los Angeles machine for the mechanical treatment to remove parts of the attached cement. Then they were soaked in two types of acids, namely hydrochloric and sulfuric, with different concentrations to determine the most effective or optimum molarity for about a 48 h soaking duration. Then a 2 h thermal treatment was conducted on the RCA samples. After all the treatments were done, the RCA aggregates were subjected to different types of tests to examine their properties in order to ensure their full potential in terms of their physical, chemical, mineralogical, and surface microstructure characteristics. Based on the experiment design, the study intends to examine the quality of the treated recycled aggregates generated by the combination approach as well as to investigate the optimal acid concentration and type. The results show that the proposed mechanochemical and thermal treatment reinforced the quality of the RCAs when compared to the non-treated samples. Meanwhile, HCl proved to be the optimum compared to H₂SO₄ in most examinations of the properties. In the end, better chemical qualities were validated, and the RCA qualities were improved.