Remarkable proton conducting behavior driven by synergistic effects in acid-base conjugated MOFs impregnated with...

The Coulomb force between protons and negative charges usually leads to low proton diffusion and poor proton conductivity. Herein, acid-base conjugated MOFs of UiO-66-SO₃^--NH₃⁺ were constructed by linking sulfonic acid and amine groups to an organic skeleton. According to the XPS and elemental analysis, the ratio of 2-aminoterephthalic acid/2-sulfoterephthalic acid was ∼1.9 in UiO-66-SO₃^--NH₃⁺. After introducing sulphuric acid molecules, the MOF-based electrolyte exhibited a remarkable proton conductivity of 5.40 × 10^-1 S cm^-1 and low activation energy of 0.15 eV at 100% RH and 90 °C. This remarkable proton conducting behavior was generated by the synergistic system in the MOF, which contained certain synergistic effects such as between -SO₃^-⋯H⁺⋯SO₄^2- and NH₃⁺⋯SO₄^2-, therefore possessing a Grotthuss mechanism, which facilitates facile proton transport.