Ni₃Sn₂/nitrogen-doped graphene composite with chemisorption and electrocatalysis as advanced separator modifying...

Lithium-sulfur batteries have been widely studied because of their advantages of abundant reserves, environmental friendliness, low cost andhighspecific capacity. However, the volume expansionand the low electrical conductivity of sulfur, and the shuttle effect of polysulfides limit their application. Herein,wesynthesizea two-dimensional layered Ni₃Sn₂/nitrogen-doped graphene (NG) composite asseparator modifying material for lithium-sulfur batteries. The Ni₃Sn₂formed by dual metal salts Ni(NO₃)₂·6H₂O and SnCl₂·2H₂O can adsorb polysulfide and catalyze its transformation to improve the electrochemical reaction kinetics. Moreover, the layered NG can not only disperse the Ni₃Sn₂particles, but alsoensure rapid electron transfer. Therefore, the lithium-sulfur battery with the Ni₃Sn₂/NG modified separator shows excellent electrochemical performance. At a current rate of 1 C, the lithium-sulfur battery with the Ni₃Sn₂/NG modified separator can provide a high initial discharge capacity of 1022.1 mAh g^-1and maintain a reversible specific capacity of 758.3 mAh g^-1after 400 cycles.