Optimization and modeling of ammonia nitrogen removal from anaerobically digested liquid dairy manure using vacuum...

During anaerobic digestion (AD) of liquid dairy manure, organic nitrogen converts to ammonia nitrogen (NH₃-N) and subsequently escalates the NH₃-N concentrations in manure. Among different available NH₃-N removal processes treating anaerobically digested liquid dairy manure (ADLDM), vacuum thermal stripping is reported to be an effective technique. However, none of the studies have performed multi-parameter optimization, which is of utmost significance in maximizing process efficiency. In this study, critical operational parameters for vacuum thermal stripping of NH₃-N from ADLDM were optimized and modeled for the first time via integrating grey relational analysis (GRA)-based Taguchi design, response surface methodology (RSM), and RSM-artificial neural network (ANN). The initial experimental trials conducted using the GRA coupled with Taguchi L₁₆ orthogonal array revealed the order of influence of the process parameters on NH₃-N removal as vacuum pressure (kPa) > temperature (°C) > treatment time (min) > mixing speed (rpm) > pH. The values of the first three most influential operating parameters were then further optimized and modeled using RSM and RSM-ANN models. Under the optimized conditions (temperature: 69.6 °C, vacuum pressure: 43.5 kPa, and treatment time: 87.65 min), the NH₃-N removal efficiency of 93.58 ± 0.59 % was experimentally observed and was in line with the RSM and RSM-ANN models' predicted values. While the RSM-ANN model showed a better prediction potential than did the RSM model when compared statistically. Moreover, the nutrient contents (nitrogen, N and sulfur, S) of the recovered NH₃-N as ammonium sulfate ((NH₄)₂SO₄) were in reasonable agreement with the market-available (NH₄)₂SO₄ fertilizer. The results presented in this study provide important insights into improving the treatment process performance and will help design and operate future pilot- and full-scale vacuum thermal stripping processes in dairy farms.