Fe^II spin crossover complexes containing N₄O₂ donor ligands

Spin crossover (SCO) is one of the most studied magnetic bistable phenomena because of its application in the field of multifunctional magnetic materials. Fe^II complexes in a N₆ coordination environment have been the most well-studied in terms of their SCO behaviour. Other coordination environments, notably the N₄O₂ coordination environment, has also been quite effective in inducing SCO behaviour in the corresponding Fe^II complexes. This review deals with such systems. The three ligand families that are discussed are: Jager type ligands, hydrazone based ligands and tridentate ligands having salicylaldehyde derivatives. These ligands allow the assembly of both mononuclear and multinuclear complexes that exhibit cooperative spin transitions. Also, Fe^II complexes obtained from some of these ligands are multifunctional and exhibit a coupling of optical and magnetic properties. Most of the Fe^II complexes obtained from these families of ligands are charge neutral which allows easy surface deposition. Further, modulation of these ligand families allows a fine tuning of the ligand field strength which results in varying SCO behavior. In addition some of the Fe^II complexes derived from these ligands exhibit a light induced excited spin state trapping (LIESST) effect. All of the above aspects are reviewed in this review.