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Vapor-Triggered Mechanical Actuation in Polymer Composite Films Based on Crystalline Organic Cages
Lukman O Alimi1, Fang Fang1, Basem Moosa1
1Smart Hybrid Materials (SHMs) Laboratory, Advanced Membranes and Porous Materials Center, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia.
Abstract:
The fabrication of smart materials, which can efficiently mimic biological systems through the introduction of soft components, is of great importance in the emerging fields of sensors and actuators. Herein, a smart composite film that can mechanically respond to vapors trigger then readily restores its original shape upon the removal of the stimuli is reported. This actuating composite film was prepared by mixing the highly elastic poly (vinylidene fluoride) (PVDF) polymer with the flexible and crystalline organic cages (Oba-cage) at variable concentrations. The mechanism of the mechanical response could be accurately recorded due to the ordered cage crystals. This work highlights the importance of designing smart materials at the molecular level to precisely control the response or reaction upon the introduction of different triggers, which can ultimately lead to a monumental leap in the field of soft robotics.
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