Recent advances in solution assisted synthesis of transition metal chalcogenides for photo-electrocatalytic hydrogen...

Hydrogen evolution from water splitting is considered to be an important renewable clean energy source and alternative to fossil fuels for future energy sustainability. Photocatalytic and electrocatalytic water splitting is considered to be an effective method for the sustainable production of clean energy, H₂. This perspective especially emphasizes research advances in the solution-assisted synthesis of transition metal chalcogenides for both photo and electrocatalytic hydrogen evolution applications. Transition metal chalcogenides (CdS, MoS₂, WS₂, TiS₂, TaS₂, ReS₂, MoSe₂, and WSe₂) have received intensified research interest over the past two decades on account of their unique properties and great potential across a wide range of applications. The photocatalytic activity of transition metal chalcogenides can further be improved by elemental doping, heterojunction formation with noble metals (Au, Pt, etc.), non-chalcogenides (MoS₂, In₂S₃, NiS_1-), morphological tuning, through various solution-assisted synthesis processes, including liquid-phase exfoliation, heat-up, hot-injection methods, hydrothermal/solvothermal routes and template-mediated synthesis processes. In this review we will discuss recent developments in transition metal chalcogenides (TMCs), the role of TMCs for hydrogen production and various strategies for surface functionalization to increase their activity, different synthesis methods, and prospects of TMCs for hydrogen evolution. We have included a brief discussion on the effect of surface hydrogen binding energy and Gibbs free energy change for HER in electrocatalytic hydrogen evolution.