Laccase-coupled photoelectrocatalytic system for highly efficient degradation of bisphenol A

In the present work, a hybrid advanced oxidation process that combined laccase with photoelectrocatalysis (PEC) was explored for highly efficient degradation of bisphenol A (BPA). Visible light-responsive BiVO₄ film electrode with good optical and photoelectrochemical properties was prepared via an electrodeposition method and employed as photoanode for PEC degradation of BPA. After laccase was facilely introduced into the PEC system, the BPA removal efficiency was significantly promoted, attributed to the synergistic effect of enzymatic catalysis and PEC processes. To obtain the optimum operation conditions, the effects of initial pH and applied bias potential were investigated systematically. Radicals trapping experiments revealed that •O₂^- dominated the biophotoelectrocatalytic degradation process, and the possible degradation pathway for BPA was proposed by identifying intermediates using liquid chromatography-mass spectrometry.