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Hydroboration-Oxidation of Alkenes03:08

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
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Negative Additive Manufacturing of Complex Shaped Boron Carbides
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Thermoformable Boron Nitride Based All-Ceramics.

Jason E Bice1, Echo St Germain1, Samuel J Wohlever1

  • 1Department of Mechanical and Industrial Engineering, Northeastern University; 334 Snell Engineering Center, 360 Huntington Avenue, Boston, MA, 02115, USA.

Advanced Materials (Deerfield Beach, Fla.)
|September 4, 2022
PubMed
Summary
This summary is machine-generated.

This study demonstrates thermoforming for boron nitride composite ceramics, enabling complex, thin parts. This innovation offers advanced ceramic heat spreaders for electronics, outperforming traditional metal solutions.

Keywords:
boron-based ceramicsceramic matrix compositesphononic heat transferthermal managementthermoforming

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Area of Science:

  • Materials Science
  • Ceramics Engineering
  • Manufacturing Processes

Background:

  • Thermoforming is typically limited to polymers and metals.
  • Boron-based all-ceramics present unique processing challenges.
  • Advanced thermal management solutions are needed for electronics.

Purpose of the Study:

  • To extend thermoforming to boron nitride (BN) based all-ceramics.
  • To develop a novel workflow for fabricating complex ceramic components.
  • To create high-performance, low-profile ceramic heat spreaders.

Main Methods:

  • Sintered BN composite sheets were fabricated using vibration and tape-casting photopolymerization.
  • The sheets exhibited an oriented microstructure allowing for pseudo-plastic flow during compression molding.
  • Bespoke all-ceramic heat spreaders were manufactured using a new workflow.

Main Results:

  • Thermoforming successfully produced thin, complex ceramic parts with features as small as 200 µm.
  • The processed ceramic heat spreaders demonstrated superior performance compared to metal heat sinks.
  • The developed method allows for press-fitting onto printed circuit boards.

Conclusions:

  • Thermoforming is a viable processing technique for boron nitride composites.
  • This approach enables the creation of advanced ceramic components for thermal management.
  • The methodology can be adapted for thermoforming other all-ceramics with ordered microstructures.