Related Experiment Video
Updated: Aug 29, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Protocol for rapid synthesis of high-performance ambipolar semiconducting polymers using an
Tao Shen1, Wenhao Li1, Yan Zhao1
1Laboratory of Molecular Materials and Devices, Department of Materials Science, Fudan University, 2005 Songhu Road, Shanghai 200438, China.
Abstract:
Syntheses using classic coupling reactions can be tedious, leading to a dearth of ambipolar semiconducting polymers. Here, we detail the rapid synthesis of balanced ambipolar polymers by using a carbon-hydrogen (C-H) activation strategy. Using this protocol, two C-H reactive hydrogenated monomers and six ambipolar polymers can be rapidly synthesized within 2 h via C-H activation and the optoelectronic properties of the resultant polymers can be characterized. We also describe the fabrication process and performance evaluation of the ambipolar polymers-based organic transistors. For complete details on the use and execution of this protocol, please refer to Shen et al. (2022).
Related Concept Videos
Cationic Chain-Growth Polymerization: Mechanism
Ziegler–Natta Chain-Growth Polymerization: Overview
Step-Growth Polymerization: Overview
Many natural and synthetic polymers are produced by...
Anionic Chain-Growth Polymerization: Overview
Anionic Chain-Growth Polymerization: Mechanism
Cycloaddition Reactions: MO Requirements for Photochemical Activation

