Organophosphonic Acid-Regulating Assembly of P^V-Sb^III Polyoxotungstate and Its Potential in Building a Dual-Signal...

Template-directed assembly of giant cluster-based nanomaterials is an everlasting theme in cluster science. In this work, ethylenediamine tetramethylphosphonic acid [H₈EDTPA = (POCH₂(OH)₂)₄C₂H₄N₂] and [B-α-SbW₉O₃₃]^9- were, respectively, used as an organic template and an inorganic template to prepare an organophosphonic acid-regulating P^V-Sb^III-heteroatom-inserted polyoxotungstate aggregate [H₂N(CH₃)₂]₅Na₁₁H₉[CeW₄O₁₀(HEDTPA)SbW₁₅O₅₀][B-α-SbW₉O₃₃]₂·36H₂O (1). Noteworthily, organophosphonic acid ligand not only works as an organic template leading to the assembly of a [HEDTPASbW₁₅O₅₀]^14- building block but also further bridges the sandwich-type [CeW₄O₁₀(B-α-SbW₉O₃₃)₂]^11- entity. To extend its potential application in electrochemical sensing properties, we prepared a three-dimensional 1@EGO composite (EGO = reduced graphene oxide functionalized by ethylenediamine) with porous architecture and a prominent conducting ability. Furthermore, the 1@EGO composite was explored as a modification material for glassy carbon electrodes to build a dual-signal readout electrochemical aptasensor for carcinogens, which shows much better detection performance for aflatoxin B1 compared with traditional single-signal biosensors.