Characterization and Mechanistic Study of Heavy Metal Adsorption by Facile Synthesized Magnetic Xanthate-Modified Chitosan/Polyacrylic Acid Hydrogels

A simple method was used to synthesize magnetic xanthate-modified chitosan/polyacrylic acid hydrogels that were used to remove heavy metal ions from an aqueous solution. Xanthate modification of chitosan significantly improved adsorption performance: individual adsorption capacities of the hydrogel for Cu(II), Cd(II), Pb(II), and Co(II) ions were 206, 178, 168, and 140 mg g^-1, respectively. The magnetic hydrogels had good regeneration ability and were effectively separated from the solution by use of a magnet. Adsorption kinetic data showed that the removal mechanism of heavy metal ions from the solution by magnetic hydrogels occurs mainly by chemical adsorption. The equilibrium adsorption isotherms were well-described by the Freundlich and Langmuir equations. Positive values were found for the Gibbs standard free energy and enthalpy, indicating an increase in the disorder at the solid-liquid interface during adsorption. Magnetic xanthate-modified chitosan-based hydrogels that exhibit high adsorption efficiency, regeneration, and easy separation from a solution have broad development prospects in various industrial sewage and wastewater treatment fields.