Synthesis of Aluminum Phosphate-Coated Halloysite Nanotubes: Effects on Morphological, Mechanical, and Rheological...

Polymer blending has been widely used to fabricate polymeric films in the last decade due to its superior properties to a single component. In this study, an aluminum phosphate-coated halloysite nanotube (HNTs@AlPO₄) was fabricated using a one-pot heterogeneous precipitation method, organically modified HNTs@AlPO₄ (o-HNTs@AlPO₄) was used to improve the performance of polyethylene oxide/poly(butylene adipate-co-terephthalate) (PEO/PBAT) blends, and the mechanical and rheological properties of the PEO/PBAT/o-HNTs@AlPO₄ films were systematically discussed. According to our results, there is an optimal addition for adequate AlPO₄ nanoparticle dispersion and coating on the surface of HNTs, and organic modification could improve the interfacial compatibility of HNTs@AlPO₄ and the polymeric matrix. Moreover, o-HNTs@AlPO₄ may serve as a compatibilizer between PEO and PBAT, and PEO/PBAT/o-HNTs@AlPO₄ films have better mechanical and rheological properties than the PEO/PBAT blends without the o-HNTs@AlPO₄ component.