Hierarchical CoMoS_3.13/MoS₂ hollow nanosheet arrays as bifunctional electrocatalysts for overall water splitting

Hollow hetero-nanosheet arrays have attracted great attention due to their efficient catalytic abilities for water splitting. We successfully fabricated ZIF-67-derived hollow CoMoS_3.13/MoS₂ nanosheet arrays on carbon cloth in situ through a two-step heating-up hydrothermal method, in which the MoS₂ nanosheets were suitably distributed on the surface of the hollow CoMoS_3.13 nanosheet arrays. There was a distinct synergistic effect between CoMoS_3.13 and MoS₂, and a large number of defective and disordered interfaces were formed, which improved the charge transfer rate and provided abundant electrochemical active sites. CMM 0.5, with the optimal Mo doping concentration of 0.5 mmol, exhibited the best catalytic properties. The overpotential values of CMM 0.5 at 10 mA cm^-2 were only 107 and 169 mV for the HER and OER, respectively, and it had nearly 100% faradaic efficiency. A dual-electrode electrolytic cell assembled with CMM 0.5 required a voltage of only 1.507 V at 10 mA cm^-2 for overall water splitting, and it displayed remarkable long-term durable bifunctional stability.