Development of novel Core-shell impregnated polyuronate composite beads for an eco-efficient removal of arsenic

Arsenic (As) can geogenically and anthropogenically contaminate the potable water resources and undoubtedly reduces its availability for human consumption. To circumvent this predicament, present study focuses on the development of a novel biosorbent by impregnating calcium cross-linked polyuronate (alginate) beads (CABs) with bilayer-oleic coated magnetite nanoparticles (CAB@BOFe) for As(V) removal. Initially, the system parameters (i.e., adsorbents dose (0.1- 3.0 g L^-1), pH (4.0-13), reaction times (0-180 min) and sorbate concentrations (10-150 µg L^-1)) were optimized to establish adsorbent at the lab-scale. CAB@BOFe had higher monolayer (ad)sorption capacity (∼62.5 µg g^-1, 120 min) than CABs (∼17.9 µg g^-1, 180 min). Electrostatic/Ion-dipole interactions and surface-complexation mechanisms mediated As(V) sorption onto CAB@BOFe mainly obeyed Langmuir isotherm (R² ∼ 0.9) and well described by intraparticle diffusion process. Furthermore, it demonstrated an excellent arsenate removal performance from the single/multiple anionic contaminants simulated water samples which supported its prospective field applicability.