Fullerene-Derived Carbon Nanotubes and Their Electrocatalytic Properties in Oxygen Reduction and Zn-Air Batteries

Carbon-based materials with superior electrochemical performances have been prepared from fullerenes by releasing their intrinsic advantages such as pentagon defects and π-electron carbons. To the best of our knowledge, fullerene-derived carbon nanotubes (CNTs) and their electrochemical behavior have not been experimentally investigated. In this work, in situ growth of CNT composites from fullerene is realized via a self-catalyzed process by employing an Fe-decorated fullerene (ferrocenylpyrrolidine C₆₀) as the precursor and NH₃ as the pyrolysis atmosphere. The results show that the in situ Fe doping in fullerene, the self-assembly of fullerene molecules, the pyrolysis temperature, and the NH₃ flow play essential roles in the generation of CNTs. The as-prepared MN7-10/3 CNT composite exhibits efficient oxygen reduction performance with E_1/2 = 0.82 V and E_on = 1.02 V vs the RHE. The flexible solid-state Zn-air battery constructed based on MN7-10/3 exhibits a superior power density (109.3 mW cm^-2 at 180.9 mA cm^-2) and long-term durability (the voltage remains at 95.6% of the initial value after discharging for 5000 s) compared with the benchmark Pt/C catalyst. The transformation of the Fe-decorated fullerene to CNTs reveals a new function of fullerenes and demonstrates a new solid-state synthetic method for CNTs.