Typical layered structure bismuth-based photocatalysts for photocatalytic nitrogen oxides oxidation

Traditional NO_x treatment methods require external reducing reagents and harsh reaction conditions, which is not conducive to effectively eliminate NO_x at low concentration, especially at ppb levels. Fortunately, low concentration NO_x can be removed by photocatalytic oxidation under mild reaction conditions. Bismuth (Bi)-based photocatalysts with the layered structure have obtained considerable concerns of photocatalytic NO_x oxidation. This review focused on typical layered Bi-based photocatalysts (Bi₂WO₆, Bi₂O₂CO₃, BiOY (YCl, Br, and I), BiOIO₃, and BiOCOOH) with the structure of [Bi₂O₂]²⁺ layer for photocatalytic NO_x oxidation. The strategies (morphological control, defect engineering, heterostructure construction, etc.) to improve photocatalytic oxidation activity were summarized. Furthermore, the mechanism involving various free radicals (hydroxyl radical, superoxide radical, etc.) of photocatalytic oxidation of NO_x was proposed. In addition, the non-NO₂ selectivity was also illuminated. Lastly, the current drawbacks and further research directions for photocatalytic NO_x oxidation were elaborated. The development of photocatalysts with high photocatalytic activity, wide light absorption range, and non-NO₂ selectivity is the focus of future research. This review aims to provide a pandect and theoretical guidance for the practical application of photocatalytic oxidation of NO_x.