Inline imaging reveals evolution of the size distribution and the concentration of microbubbles in dissolved air...

Dissolved air flotation (DAF) is an efficient process to remove impurities from fresh or salt water. As the removal is based on the agglomeration of impurities on the generated microbubbles, the size distribution and concentration of air bubbles are key parameters in dissolved air flotation. However, the development of microbubbles in the whole flotation process remains unexplored. In this study, we show that state-of-the-art inline microscopy enables the image acquisition of bubbles in DAF. Based on image analysis, thousands of microbubbles (10-200 µm) were analyzed within 6-12 min experiments. Consequently, bubble size distributions and bubble concentrations can be determined with moderate effort. Bubble size distributions were measured in a lab-scale DAF comprising a saturation unit, a decompression valve in/after which the bubbles are formed, and the actual flotation tank. The state of the microbubbles is not only determined at different positions within the tank but also in the supply pipe from the decompression valve to the tank. All bubble size distributions were unimodal and can be described well with Burr XII distributions. For fresh water, bubble size increased while bubble concentration decreased along the supply pipe between the decompression valve and the inlet of the flotation tank, indicating bubble coalescence. Compared to freshwater, saltwater inhibited this bubble coalescence in the pipe. Within the flotation tank, the bubble size did not change drastically for neither salt- nor freshwater. However, the bubble concentration decreased for both waters, which could be explained by dilution effects. Our results demonstrate that the developed inline method is a promising tool to study the evolution of microbubbles in flotation systems. Further, it might also be applied to investigate microbubbles in other processes such as fermentation, decomposition of organic compounds, and fouling mitigation in membranes.