Comparison of cadmium adsorption by hydrochar and pyrochar derived from Napier grass

Biochar (e.g. pyrochar and hydrochar) is considered a promising adsorbent for Cd removal from aqueous solution. Considering the vastly different physicochemical properties between pyrochar and hydrochar, the Cd²⁺ sorption capacity and mechanisms of pyrochars and hydrochars should be comparatively determined to guide the production and application of biochar. In this study, the hydrochars and pyrochars were prepared from Napier grass by hydrothermal carbonization (200 and 240 °C) and pyrolysis (300 and 500 °C), respectively, and the physicochemical properties and Cd²⁺ sorption performances of biochars were systematically determined. The pyrochars had higher pH and ash content as well as better stability, while the hydrochars showed more oxygen-containing functional groups (OFGs) and greater energy density. The pseudo second order kinetic model best fitted the Cd²⁺ sorption kinetics data of biochars, and the isotherm data of pyrochar and hydrochar were well described by Langmuir and Freundlich models, respectively. In comparison with hydrochar, the pyrochar exhibited better Cd²⁺ sorption capacity (up to 71.47 mg/g). With increasing production temperature, the Cd²⁺ sorption capacity of pyrochar elevated, while the reduction was found for hydrochar. The mineral interaction, complexation with surface OFGs, and coordination with π electron were considered the main mechanisms of Cd²⁺ removal by biochars. The minerals interaction and the complexation with OFGs was the dominant mechanism of Cd²⁺ removal by pyrochars and hydrochars, respectively. Therefore, the preparation technique and temperature have significant impacts on the sorption capacity and mechanisms of biochar, and pyrochar has better potential for Cd²⁺ removal than the congenetic hydrochar.