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Updated: Aug 28, 2025

Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes
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Chemoselective Preparation of 1-Iodoalkynes, 1,2-Diiodoalkenes, and 1,1,2-Triiodoalkenes Based on the Oxidative Iodination of Terminal Alkynes

Published on: September 12, 2018

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Synthesis and Structural Verification of an ArI(OTf)2 , NO2 -Ph-I(OTf)2

Lachlan Sharp-Bucknall1, Tania1, Jason L Dutton1

  • 1Department of Biochemistry and Chemistry, La Trobe University, Melbourne, Victoria, Australia.

Angewandte Chemie (International Ed. in English)
|September 14, 2022
PubMed
Summary

Researchers synthesized and characterized a novel hypervalent iodine compound, nitro-phenyliodine(III) bis(triflate) (NO2-PhI(OTf)2). This stable and reactive species corrects long-standing misidentifications in oxidation chemistry.

Keywords:
HypervalentIodineOxidations

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