Photochemical Dearomative Cycloadditions of Quinolines and Alkenes: Scope and Mechanism Studies

Renyu Guo1, Souvik Adak1, Peter Bellotti2

  • 1Department of Chemistry, Indiana University, 800 E. Kirkwood Avenue, Bloomington, Indiana47405, United States.

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Thermal cycloadditions are reactions where the source of activation energy needed to initiate the reaction is provided in the form of heat. A typical example of a thermally-allowed cycloaddition is the Diels–Alder reaction, which is a [4 + 2] cycloaddition. In contrast, a [2 + 2] cycloaddition is thermally forbidden.
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