Characterization and photocatalytic activity of TiO₂ nanoparticles on cotton fabrics, for antibacterial masks

The in-situ impregnation of two commercial cotton fabrics (lab coat and Indiolino) with TiO₂ nanoparticles (TiO₂-NPs) was carried out. For this, two commercial cotton fabrics were dipped in titanium isopropoxide, titanium butoxide and titanium tetrachloride solutions to the TiO₂-NPs formation and in-situ TiO₂-NPs impregnation on the cotton fabric surface by the sonochemical, hydrothermal and solvothermal methods, respectively. The impregnated fabrics were characterized by ATR-FTIR, SEM-EDS, Raman, UV-Vis, DRS and tension tests. The results showed the successful formation and impregnation of TiO₂-NPs on both cotton fabrics. The leaching of TiO₂-NPs from cotton fabrics was negligible after several washing cycles. The self-cleaning properties and antibacterial activity of TiO₂-NPs functionalized cotton fabrics were assessed by photocatalytic and antibacterial tests. The photocatalytic activity was determined by the degradation of methylene blue dye under UV and solar irradiation. The materials showed good photoactivity, since MB was degraded up to 99% under solar and UV irradiations in 60 min. The bactericidal capacity of the TiO₂-NPs on fabrics, evaluated in-situ by SEM, showed that Indiolino presented the best antibacterial properties against Escherichia coli and Bacillus pumilus.