Hydrothermal and photocatalytic synergistic pretreatment to improve the full utilization of corn stalk

In this study, the hydrothermal and photocatalytic synergistic pretreatment for improving the full component utilization of corn stalk based on lignin first biorefining was employed to generate carbohydrates and obtain modified lignin. The results showed that the highest lignin removal ratio (40.70 %) and cellulose retention ratio (92.64 %) were obtained due to the smallest energy gap (6.05 eV) and the largest penetration distance (1.73 Å) between GVL and the lignin. And the yield of carbohydrates increased from 1.95 % to 58.17 % after hydrothermal pretreatment at 180 ℃. Furthermore, the modified lignin enhanced the flocculation effect, resulting in the increase of the removal of safranine-T by 6 times. In addition, the chemical and physical properties of modified lignin were studied and the mechanism of photocatalysis modification was explored. The research provides a new pretreatment method for the utilization of biomass and simultaneously achieves carbohydrate enrichment in bio-oil and purification of dye wastewater.