Carbon Surface Chemistry: New Insight into the Old Story

The enormous complexity of the carbon material family has provoked a phenomenological approach to develop its potential in different applications. Although the electronic, chemical, mechanical, and magnetic properties of carbon materials have been widely discussed based on defect control engineering, there is still a lack of fundamental understanding of the carbon surface chemistry, which leads to many controversial conclusions. Here, by analyzing various defects on carbon surface, some commonly neglected aspects and misunderstandings in this field are pointed out, clarifying how surface chemistry affects the chemical behaviors of carbon in some specific chemical reactions. With this full-scale consideration of the carbon surface chemistry, the behaviors of carbon materials with various functions can be well defined, which is indispensable for their scalable applications. Perspectives on future developments of carbon surface chemistry are also provided to enable practically accessible design of advanced carbon in those applications.