Synergistic Effect of Work Function and Acoustic Impedance Mismatch for Improved Thermoelectric Performance in...

The preparation of composite materials is a promising methodology for concurrent optimization of electrical and thermal transport properties for improved thermoelectric (TE) performance. This study demonstrates how the acoustic impedance mismatch (AIM) and the work function of components decouple the TE parameters to achieve enhanced TE performance of the (1-z)Ge_0.87Mn_0.05Sb_0.08Te-(z)WC composite. The simultaneous increase in the electrical conductivity (σ) and Seebeck coefficient (α) with WC (tungsten carbide) volume fraction (z) results in an enhanced power factor (α²σ) in the composite. The rise in σ is attributed to the creation of favorable current paths through the WC phase located between grains of Ge_0.87Mn_0.05Sb_0.08Te, which leads to increased carrier mobility in the composite. Detailed analysis of the obtained electrical properties was performed via Kelvin probe force microscopy (work function measurement) and atomic force microscopy techniques (spatial current distribution map and current-voltage (I-V) characteristics), which are further supported by density functional theory (DFT) calculations. Furthermore, the difference in elastic properties (i.e., sound velocity) between Ge_0.87Mn_0.05Sb_0.08Te and WC results in a high AIM, and hence, a large interface thermal resistance (R_int) between the phases is achieved. The correlation between R_int and the Kapitza radius depicts a reduced phonon thermal conductivity (κ_ph) of the composite, which is explained using the Bruggeman asymmetrical model. Moreover, the decrease in κ_ph is further validated by phonon dispersion calculations that indicate the decrease in phonon group velocity in the composite. The simultaneous effect of enhanced α²σ and reduced κ_ph results in a maximum figure of merit (zT) of 1.93 at 773 K for (1-z)Ge_0.87Mn_0.05Sb_0.08Te-(z)WC composite for z = 0.010. It results in an average thermoelectric figure of merit (zT_av) of 1.02 for a temperature difference (ΔT) of 473 K. This study shows promise to achieve higher zT_av across a wide range of composite materials.