Related Experiment Video
Updated: Aug 28, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
Hydrogen-bonded aromatic amide macrocycles: synthesis, properties and functions.
Zejiang Liu1, Yidan Zhou1, Lihua Yuan1
1College of Chemistry, Key Laboratory of Radiation Physics and Technology of Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064, China. lhyuan@scu.edu.cn.
This review summarizes hydrogen-bonded aromatic amide (H-bonded aramide) macrocycles, detailing their synthesis, properties, and applications in areas like molecular recognition and artificial ion channels.
Area of Science:
- Supramolecular Chemistry
- Organic Chemistry
Background:
- Hydrogen-bonded aromatic amide (H-bonded aramide) macrocycles are nearly planar cyclic compounds.
- These macrocycles feature consecutive intramolecular hydrogen bonds and aromatic residues, leading to significant host-guest chemistry.
Purpose of the Study:
- To provide a comprehensive review of the synthesis, properties, and functions of H-bonded aramide macrocycles and their derivatives.
- To categorize H-bonded aramide macrocycles based on interior and exterior hydrogen bonding motifs.
Main Methods:
- Classification of macrocycles into interior and exterior hydrogen bonding motifs.
- Summarization of synthesis strategies and self-assembly processes.
- Review of host-guest interaction complexation.
Main Results:
- Detailed overview of H-bonded aramide macrocycles, including their constitutional patterns.
- Exploration of applications such as molecular recognition, artificial ion channels, soft materials, supramolecular catalysis, and artificial molecular machines.
- Highlighting the nascent stage of development for these macrocycles.
Conclusions:
- H-bonded aramide macrocycles offer diverse applications due to their unique structural and chemical properties.
- Further research in this field is expected to yield new opportunities and advancements.
- This review serves as a valuable resource for researchers in supramolecular chemistry.
More Related Videos
06:35Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
11:45Preparation of Stable Bicyclic Aziridinium Ions and Their Ring-Opening for the Synthesis of Azaheterocycles
Published on: August 22, 2018
Related Concept Videos
Five-Membered Heterocyclic Aromatic Compounds: Overview
Structures of Carboxylic Acid Derivatives
Carboxylic acid derivatives contain an acyl group attached to a heteroatom such as chlorine, oxygen, or nitrogen. The carbonyl carbon and oxygen are both sp2-hybridized with an unhybridized p orbital.
The three sp2 orbitals of the carbonyl carbon form three σ bonds, one each with the carbonyl oxygen, the α carbon, and the heteroatom, whereas the other two sp2 orbitals of the carbonyl oxygen are occupied by the lone pairs. Further, the...
Aromatic Hydrocarbon Anions: Structural Overview
Due to the absence of continuous...
Basicity of Heterocyclic Aromatic Amines
Structure of Amines
Aromatic Hydrocarbon Cations: Structural Overview
Removing one hydrogen from the intervening CH2 group...