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Updated: Aug 28, 2025
Development of Efficient OLEDs from Solution Deposition
Published on: November 4, 2022
Exceeding 30 % External Quantum Efficiency in Non-doped OLEDs Utilizing Solution Processable TADF Emitters with High
Guimin Zhao1, Dan Liu1, Panpan Wang1
1Jiangsu Province Hi-Tech Key Laboratory for Bio-Medical Research, Jiangsu Engineering Laboratory of Smart Carbon-Rich Materials and Device, School of Chemistry and Engineering, Southeast University, Nanjing, Jiangsu, 211189, China.
Abstract:
Strategies to enhance the ratio of the molecular horizontal emitting dipole orientation (Θ∥ ) for thermally activated delayed fluorescence (TADF) emitters have unlocked the full potential of efficiencies for the evaporated devices, which, however, remain elusive for the solution-processed ones. Here, a strategic molecular design for solution processable TADF emitters featuring high Θ∥ s is proposed by attaching flexible chains ended with bipolar 9,9'-spirobi[fluorene] subunits as anchoring groups onto TADF emitting core. It's unveiled that the anchoring groups not only enhance the horizontal orientation via enlarging molecular planarity, but also benefit the high photoluminescence in pristine films. The corresponding non-doped solution processable OLEDs substantiate an unprecedented maximum external quantum efficiency (EQEmax )>30 %. Meanwhile, combining these compounds as TADF sensitizers, and multiple resonance final emitter, solution-processed OLEDs achieve an EQEmax of 25.6 % with a narrow full width at half maximum of 29 nm.
