Natural wood-derived free-standing films as efficient and stable separators for high-performance lithium ion...

A sustainable and low-cost separator is highly required for electrochemical energy storage systems. Herein, a type of modified natural wood film with excellent mechanical properties, ion conductivity and thermal stability is fabricated for high-performance lithium ion batteries. Using the modified natural wood film as a separator, the fabricated symmetric cell exhibits a more stable and lower plating/stripping voltage for Li than that of the cell with a commercialized polypropylene (PP) separator. The LiFePO₄/Li half-cell with the modified wood film separator shows a small polarization voltage and high discharge capacity because of the multi-level nanostructure and abundant functional groups of the modified wood films. The results suggest that the modified wood films are a promising candidate for use as separators in lithium ion batteries. As desired, the LiFePO₄/Li half-cells with the modified wood film separator deliver much higher discharge capacities and more stable Coulomb efficiency over two hundred charge/discharge cycles than the cell based on the PP separator. The present work systematically investigate the feasibility of abundant and cheap natural wood-derived materials for use as efficient separators instead of synthetic polymers for high-performance lithium ion batteries with long cycle life.