A review of size engineering-enabled electrocatalysts for Li-S chemistry

Li-S batteries (LSBs) have received extensive attention owing to their remarkable theoretical capacity (1672 mA h g^-1) and high energy density (2600 W h kg^-1), which are far beyond those of the state-of-the-art Li-ion batteries (LIBs). However, the retarded sulfur reaction kinetics and fatal shuttle effect have hindered the practical implementations of LSBs. In response, constructing electrocatalysts for Li-S systems has been considered an effective strategy to date. Particularly, size engineering-enabled electrocatalysts show high activity in the sulfur redox reaction, considerably contributing to the latest advances in Li-S system research. In this tutorial review, we provide a systematic summary of nano- to atomic-scale electrocatalysts employed in Li-S chemistry, aiming at figuring out the working mechanism of size engineering-enabled electrocatalysts in the sulfur redox reaction and guiding the rational construction of advanced LSBs toward practically viable applications.