Does gold behaves as hydrogen? A joint theoretical and experimental study
Zhengbo Qin1, Jiangle Zhang1,2, Chen Wang1
1Anhui Province Key Laboratory of Optoelectric Materials Science and Technology, Department of Physics, Anhui Normal University Wuhu Anhui 241000 China wave0403@163.com.
Abstract:
It has been established that the noble-metal-H analogue has been found in a large number of noble-metal-ligand clusters in view of geometric and electronic structures. Here, we demonstrated a different view of noble-metal-H analogue between noble-metal and hydrogen in M(SCH3)2 - (M = Cu, Ag, Au and H) systems. Although H(SCH3)2 - is a typical ion-hydrogen bonding cluster dramatically different from the chemical bonding clusters of M(SCH3)2 - (M = Cu, Ag and Au), the comparison of the two typical bonding patterns has not yet been fully investigated. Through a series of chemical bonding analyses, it is indicated that the evolution has been exhibited from typical ionic bonding in Cu(SCH3)2 - to a significant covalent bonding nature in Au(SCH3)2 - and hydrogen bonding dominating in H(SCH3)2 -. The comparison of M(SCH3)2 - (M = Cu, Ag and Au) with H(SCH3)2 - illustrates the differences in bonding between noble metals and hydrogen, which are mainly related to their diverse atomic orbitals participating in chemical bonding.
