Infrared tunable, two colour-band photodetectors on flexible platforms using 0D/2D PbS-MoS₂ hybrids

Two-dimensional (2D) MoS₂ nanosheets have been integrated with zero-dimensional (0D) PbS quantum dots to achieve a superior optical response extending to the short-wavelength infrared region along with a broadband visible response for multispectral photodetection. The 0D/2D hybrid nanostructures have been synthesized by a one pot, stabilizer-free solvothermal growth process. Microscopic and spectroscopic studies confirmed the formation of PbS QD decorated semiconducting 2H-MoS₂ layers. The size tunable absorption features with longer photo-generated carrier lifetime of synthesized hybrid nanostructures indicate that the integration of PbS QDs in MoS₂ could be a viable approach for fabricating two-colour band photodetectors, viz. visible broadband and wavelength selective short-wave IR photodetectors. Devices have also been demonstrated on polyethylene terephthalate substrates using a solution-based synthesis technique for flexible and ultrathin optoelectronic device applications. The photodetection performance of fabricated devices suggests that the synergic 0D/2D hybrid nanostructures are significantly superior to solution processed hybrid devices operating in the infrared region. The successful integration of 0D QDs in 2D materials may pave the way for novel, high performance, next-generation CMOS compatible flexible photonic devices.