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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Formate Dehydrogenase Mimics as Catalysts for Carbon Dioxide Reduction
Thibault Fogeron1, Yun Li1, Marc Fontecave1
1Laboratoire de Chimie des Processus Biologiques, UMR 8229 CNRS, Collège de France, Paris Sorbonne University, 11 Place Marcelin Berthelot, CEDEX 05, 75231 Paris, France.
Abstract:
Formate dehydrogenases (FDH) reversibly catalyze the interconversion of CO2 to formate. They belong to the family of molybdenum and tungsten-dependent oxidoreductases. For several decades, scientists have been synthesizing structural and functional model complexes inspired by these enzymes. These studies not only allow for finding certain efficient catalysts but also in some cases to better understand the functioning of the enzymes. However, FDH models for catalytic CO2 reduction are less studied compared to the oxygen atom transfer (OAT) reaction. Herein, we present recent results of structural and functional models of FDH.
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