Dilute Hybrid Electrolyte for Low-Temperature Aqueous Sodium-Ion Batteries

A hybrid electrolyte based on low-concentration sodium nitrate with glycerol as an additive was proposed for aqueous sodium-ion batteries (ASIBs) towards low-temperature performance. Based on this dilute hybrid electrolyte and configured by bimetallic Prussian blue analogue (Ni₂ ZnHCF) cathode and 3,4,9,10-perylenetetracarboxylic diimide (PTCDI) anode, the full cell demonstrated surprising cycle performance with a specific capacity of 60 mAh g^-1 (>800 cycles) and achieved prominent performance at low temperature. Glycerol effectively expanded the electrochemical stability window of the hybrid electrolyte to 2.7 V from formation of strong hydrogen bonds with water molecules and realized the operation of the cell at low temperature, delivering a stable reversible capacity of 40 mAh g^-1 at -10 °C. The hybrid electrolyte of glycerol-water provides a new alternative in development of low-cost, long-lifespan, and low-temperature ASIBs and other aqueous battery systems.