Enhanced dewaterability of sludge by Fe(II)-sludge biochar activate persulfate

Sludge biochar supported Fe(II) (Fe(II)-SBC) was successfully prepared using waste activated sludge as peroxydisulfate (PDS) activator to condition sludge for deep dewatering. The experimental results showed that Fe(II)-SBC with FeO on it could effectively active PDS to produce $$ and $$. The radicals could destroy the structure of sludge cells and extracellular polymeric substance (EPS), transformed the hydrophilic and tightly bound EPS into soluble-EPS, degrade partial proteins and polysaccharides and released bound water. The negatively charged groups on sludge floc were dripped off by $$/$$ or neutralized with Fe²⁺, Fe³⁺, H⁺, or Fe(II)-SBC, leading to an increase in zeta potential to -2.24 mV and sludge destabilization. The residual Fe(II)-SBC served as a skeleton builder that decreased the compression coefficient of the sludge cake to 0.75. Under the combined functions, the CST and SRF were reduced by 70% and 82.7%, respectively, and W_c was reduced to 72.4%. The byproducts of Fe³⁺ and SO₄^2- finally remained in sludge cake in the form of NaFeSi₂O₆ and CaSO₄.