Electrified ceramic membrane actuates non-radical mediated peroxymonosulfate activation for highly efficient water...

Electrified ceramic membranes (ECMs) achieve high water decontamination efficiency mainly through implementing in situ radical-mediated oxidation in membrane filtration, whereas ECMs leveraging non-radical pathways are rarely explored. Herein, we demonstrated a Janus ECM realizing ultra-efficient micropollutant (MP) removal via electro-activating peroxymonosulfate (PMS) in a fast, flow-through single-pass electro-filtration. The Janus ECM features two separate palladium (Pd) functionalized electrocatalytic reaction zones engineered on its two sides. We confirmed that the PMS/electro-filtration system induced non-radical pathways for MP degradation, including singlet oxygenation and mediating direct electron transfer (DET) from MP to PMS. Under the design of the ECM featuring dual electrocatalytic reaction zones in the ceramic membrane intrapores, the Janus ECM showed over one-fold increase in micropollutant removal rate as 94.5% and lower electric energy consumption as 1.78 Wh g^-1 MP in the PMS electro-activation process, as compared with the conventional ECM assembly implementing only half-cell reaction. This finding manifested the Janus ECM configuration advantage for maximizing the PMS electro-activation efficiency via singlet oxygenation intensification and direct usage of cathode for DET mediation. The Janus ECM boosted the PMS electro-activation and water decontamination efficiency by enhancing the convective mass transfer and the spatial confinement effect. Our work demonstrated a high-efficiency PMS electro-activation method based on electro-filtration and maximized the non-radical mediated PMS oxidation for MP removal, expanding the ECM filtration strategies for water decontamination.