Related Experiment Video
Updated: Aug 27, 2025

08:16
Ice Generation and the Heat and Mass Transfer Phenomena of Introducing Water to a Cold Bath of Brine
Published on: March 13, 2017
14.0K
Effect of diffusion kinetics on the ice nucleation temperature distribution
Lorenzo Stratta1, Andrea Arsiccio1, Roberto Pisano2
1Molecular Engineering Laboratory (molE), Department of Applied Science and Technology, Politecnico di Torino, 24 corso Duca degli Abruzzi, 10129, Turin, Italy.
Scientific Reports
|September 29, 2022
Summary
Water
Area of Science:
- Water nucleation is critical across diverse scientific fields, including meteorology, glaciology, biology, and astrophysics.
Background:
- Heterogeneous nucleation of ice in water is a fundamental process with broad implications.
- Understanding the factors influencing ice nucleation is essential for various scientific disciplines.
Purpose of the Study:
- To investigate the influence of diffusion kinetics on heterogeneous ice nucleation in water.
- To explore how variables like thawing temperature and residence time affect nucleation regularity.
Main Methods:
- Differential scanning calorimetry (DSC) was employed for freeze/thaw cycle analysis.
- The study systematically varied thawing temperature and residence time above 0°C.
Main Results:
- Thawing temperature and residence time significantly impact the width of ice nucleation temperature distributions.
- Enhanced nucleator diffusion led to broader, more scattered distributions.
- Limited nucleator diffusion resulted in narrower, more regular distributions.
Conclusions:
- Diffusion kinetics of external nucleators play a key role in heterogeneous ice nucleation.
- A theoretical framework is proposed, linking diffusion kinetics' temperature dependence to nucleation behavior.
Related Concept Videos
Extraction: Partition and Distribution Coefficients
2.7K
The distribution law or Nernst's distribution law is the law that governs the distribution of a solute between two immiscible solvents. This law, also known as the partition law, states that if a solute is added to the mixture of two immiscible solvents at a constant temperature, the solute is distributed between the two solvents in such a way that the ratio of solute concentrations in the solvents remains constant at equilibrium.
For extracting a solute from an aqueous phase into an...
For extracting a solute from an aqueous phase into an...
2.7K
Diffusion
196.3K
Diffusion is the passive movement of substances down their concentration gradients—requiring no expenditure of cellular energy. Substances, such as molecules or ions, diffuse from an area of high concentration to an area of low concentration in the cytosol or across membranes. Eventually, the concentration will even out, with the substance moving randomly but causing no net change in concentration. Such a state is called dynamic equilibrium, which is essential for maintaining overall...
196.3K
Passive Diffusion: Overview and Kinetics
641
Passive diffusion is a critical process that allows small lipophilic drugs to cross the cell membrane along a concentration gradient. This mechanism's efficiency depends on four primary factors: the membrane's surface area, the drug's lipid-water partition coefficient, the concentration gradient, and the membrane's thickness.
When administered orally, drugs establish a substantial concentration gradient between the gastrointestinal (GI) lumen and the bloodstream, expediting...
When administered orally, drugs establish a substantial concentration gradient between the gastrointestinal (GI) lumen and the bloodstream, expediting...
641
Temperature Dependence on Reaction Rate
82.7K
The Collision Theory
Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. This premise is the basis for a theory that explains many observations regarding chemical kinetics, including factors affecting reaction rates.
The collision theory is based on the postulates that (i) the reaction rate is proportional to the rate of reactant collisions, (ii) the reacting species collide in an orientation allowing contact between...
Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. This premise is the basis for a theory that explains many observations regarding chemical kinetics, including factors affecting reaction rates.
The collision theory is based on the postulates that (i) the reaction rate is proportional to the rate of reactant collisions, (ii) the reacting species collide in an orientation allowing contact between...
82.7K
Effect of Temperature Change on Reaction Rate
4.3K
The Arrhenius equation,
4.3K
Factors Affecting Activity Coefficient
886
The extended Debye-Hückel equation indicates that the activity coefficient of an ion in an aqueous solution at 25°C depends on three partially interdependent properties: the ionic strength of the solution, the charge of the ion, and the ion size.
The activity coefficient value for an ion is close to one when the solution has almost zero ionic strength, i.e., when the solution shows close to ideal behavior. As the ionic strength of the solution increases from 0 to 0.1 mol/L, a...
The activity coefficient value for an ion is close to one when the solution has almost zero ionic strength, i.e., when the solution shows close to ideal behavior. As the ionic strength of the solution increases from 0 to 0.1 mol/L, a...
886

