Triethanolamine-assisted synthesis of NiFe layered double hydroxide ultrathin nanosheets for efficient oxygen...

Water electrolysis is a promising technique for producing high-quality hydrogen, the application of which is impeded by the sluggish oxygen evolution reaction (OER) process. In this study, ultrathin nickel-iron layered double hydroxide (NiFe LDH) nanosheets were successfully synthesized through a facile hydrothermal reaction with the assistance of triethanolamine (TEA). Morphological and structural characterizations revealed that the presence of TEA modified the morphology of NiFe LDH, facilitated the synthesis of high-purity NiFe LDH, improved the crystallinity of NiFe LDH and resulted in a slight decrease in specific surface area. X-ray photoelectron spectroscopy (XPS) analysis demonstrated the modulation of the electronic structure engendered by the addition of TEA, with nickel and iron appearing in high valence state in the resulting NiFe LDH nanosheets. The as-prepared NiFe LDH nanosheets possessed outstanding OER activity with fast kinetics, exhibiting a low overpotential of 261 mV to achieve a current density of 10 mA cm^-2 and a small Tafel slope of 32.5 mV dec^-1 in 1 M KOH. The excellent OER performance and rapid OER kinetics are mainly attributed to the high-valence Ni and Fe rather than the modification in the morphology and microstructure.